Please help me writing a for loop to display different permutations and combination numbers

I have four images , and i wanted to assign with any of number(1 to 4) and present with combination of different image

To do this I am working on creating a matrix

I want to create a matrix like where first column is for image number, second column is for assigning number and third for any of other symbols

1 1 2

1 1 3

1 1 4

2 2 1

2 2 3

2 2 4

3 3 1

3 3 2

3 3 4

[Jan]

The question is not clear yet: What is a "assigning number"? What is the general pattern your matrix should have? Are the first two columns identical in every case?