If I'm understanding correctly, the problem is that, just as with ordinary non-parallel MATLAB, the random numbers on each worker are the same each time you start up (the random number generators are set up using each worker's labindex). If you are doing one calculation in one session, that's fine. But if you want to combine results of MC simulations from multiple sessions, and be able to treat them as statistically independent, then obviously that is a problem.
If that's right, then the solution is to (re)initialize the generator differently on each worker each time you start it up, using pctrunonall. "Differently on each worker each time you start it up" can be achieved using something involving 'shuffle', but it's theoretically possible to get the same initialization in two places by random chance. So a better idea is a combination of labindex and some sort of unique session number.
Just as in the serial case, you could use rng(i), where i is based on the lab index and the session number. But there are parallel generators that are designed specifically for this kind of large-scale MC simulation context: mrg32k3a and mlfg6331_64. If you know how many workers and sessions, then do something like this:
stream = RandStream.create('mrg32k3a','NumStreams',workers*sessions, ...
That gives you statistical independence across workers, across sessions. That will work for those two generators. With a non-parallel generator like mt19937ar, your only course would be to use different seeds, but again you could base the seeds on labindex and the session number.
Hope this helps.