Finding out specific color area in image

I need to find the area of a region having a specific color by taking screenshots from a video. An example screenshot is http://postimg.org/image/6gpk9013b/
How to find the area of the spilled oil ? Also this needs to be done for multiple screenshots from a video of spilling. Can this be done simultaneously on Matlab or should I get screenshots using a different software and then upload in Matlab ?

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Thanks Image Analyst\m/. This is a big project I have taken in a field quite unknown to me. Will try these methods.

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